APPENDIX

PART VI

CHEMICAL & STRUCTURAL TRENDS FOR CLASSIFICATION

  1. Oxygen Content:
  2. Carbonaceous chondrites are oxygen-rich with most of the iron combined as silicates, magnetite, or water. Ordinary chondrites have about half their iron in the oxide form with the rest in troilite or metal. Enstatite chondrites are oxygen-poor with all the iron in metal or sulfide form. R chondrites have a high degree of Fe oxidation.
  3. CI-normalized refractory-lithophile abundance ratio:
  4. Carbonaceous chondrites have a ratio of 1.00–1.35 (CV = 1.33, CK = 1.11–1.33, CO,CM = 1.11, CR = 1.00), R chondrites 0.85, ordinary chondrites 0.77–0.82, and enstatite chondrites ~0.6.
  5. Fine-grained matrix/chondrule modal abundance ratio:
  6. Carbonaceous chondrites have a ratio of 0.5–7.0, ordinary chondrites ~0.3, enstatite chondrites essentially none, and R chondrites 1.6 ±0.9.
  7. Abundance of isotopically heterogeneous refractory inclusions:
  8. Carbonaceous chondrites have a ratio of ~0.5–5.0 vol%, ordinary chondrites have a negligible amount, enstatite chondrites a negligible amount, and R chondrites essentially none.
  9. Whole rock O-isotope composition:
  10. Carbonaceous chondrites are much below the terrestrial fractionation line (TFL), ordinary chondrites are above the TFL, enstatite chondrites are on the TFL, and R chondrites are much above the TFL. The CO and CK groups share a common O-isotopic composition.
  11. CI-normalized Se/Sb concentration ratios:
  12. Carbonaceous chondrites have a ratio of 0.6–0.9, ordinary chondrites 0.9–1.1, enstatite chondrites 1.0–1.2, and R chondrites 1.5 ±0.2.
  13. Molar An of plagioclase:
  14. Carbonaceous chondrites have a high molar, ordinary chondrites have a low molar, enstatite chondrites have a very low molar, and R chondrites have a low molar.
  15. Abundance of opaque mineral-rich porphyritic chondrules:
  16. Carbonaceous chondrites have a large abundance, ordinary chondrites have few, enstatite chondrites have a low to moderate abundance, and R chondrites have few.
  17. Ratio of Iron to Silicon:
  18. Subdivides ordinary chondrites into subgroups H, L, and LL, and the enstatite chondrites into subgroups EH and EL.
  19. Ratio of Magnesium to Silicon:
  20. Separates the carbonaceous, ordinary, and enstatite chondrites. Carbonaceous chondrites have average ratios of 1.05. Ordinary chondrites have ratios of 0.97, 0.92, and 0.92 for H, L, and LL groups, respectively. Enstatite chondrites have ratios of 0.73 and 0.88 for EH and EL groups, respectively.
  21. Ratio of Calcium to Silicon:
  22. Subdivides carbonaceous chondrites into subgroups CI, CM, CR, CO, CK, CV, and CH.
  23. CV oxidized Bali-like and Allende-like, and reduced subgroups are separated by FeNi-metal, sulfide, and magnetite abundances (after Bland et al., 2000):
    • Allende-like have low FeNi-metal, sulfides, and magnetite; metal and sulfides are Ni-rich.
    • Bali-like have variable to high magnetite, low to absent metal, and low sulfides; metal and sulfides are mostly Ni-rich.
    • reduced CVs have intermediate magnetite, high metal, and high sulfides; metal and sulfides are mostly Ni-poor.
  24. Ratio of low-temperature metals (e.g., Pd and Au) to Ir:
  25. Ratios are higher in EL than in EH chondrites.
  26. Chondrule Size (Brearley and Jones, 1998):
  27. Average diameter (mm) decreases in the order CV>LL>CR=CK=L>EL=K>R>CM=H>EH>CO>CH.
  28. Petrologic Type:
  29. Type 3 represents unaltered material, while lower numbers represent progressive alteration by aqueous conditions and higher numbers represent progressive alteration by thermal metamorphism. As metamorphic alteration increases to type 7, a number of chemical and physical changes occur:
  • olivine and pyroxene become more homogenous
  • pyroxene changes from low-temperature clinopyroxene to high-temperature orthopyroxene
  • amount of crystalline feldspar increases at the expense of glass, then decreases after vitrification
  • feldspar coarsens from type 6 to 7, becoming >0.1 mm in size
  • fine-grained matrix becomes transparent and recrystallizes into a coarser texture
  • bulk carbon and bulk water content decrease
  • Ca range in Wollastonite increases from 0.4–1.2 in types 3 and 4, to 1.2–1.6 in type 5, and to 1.6–2.2 in type 6
  • CaO in low-Ca pyroxenes increases from <1.0 wt% to >1.0 wt% from type 6 to 7
  • chondrules merge into surrounding material and become only relics by type 7, while like-metal grains coalesce and exhibit an even dispersion
  • TL sensitivity increases with higher petrologic type, while decreasing at higher shock levels

Petrographic Types of CO3 Chondrites
(after Sears et al., 1991)
  TL sens (120°C)
3.0 <0.017
3.1     .017–  .030
3.2     .030–  .054
3.3     .054–  .100
3.4     .100–  .170
3.5     .170–  .300
3.6     .300–  .540
3.7     .540–1.000
3.8   1.000–1.700
3.9 >1.700

It is thought that the TL sensitivity technique is not applicable below subtype 3.2 because feldspar may have been dissolved during the aqueous alteration process. This classification method has now been superceded by more sensitive techniques that are able to measure the peak metamorphic temperatures, and thus enable the direct comparison of petrologic types between chemical classes. To discriminate among subtypes below type 3.2, it has been shown that the Cr content of ferroan olivine is an excellent indicator of metamorphism. Chromite exsolves from olivine in the incipient stages of metamorphism, initially producing heterogeneous Cr2O3 contents, and eventually low-Cr olivine. In a study by Chizmadia and Bendersky (2006), they determined that this sequence progresses from type 3.0, corresponding to high Cr2O3 contents of 0.3–0.4 wt%, to type 3.2, in which Cr2O3 constitutes less than 0.1 wt%. The gap between these subtypes represents type 3.1.


Diagram courtesy of J. N. Grossman & A. J. Brearley
Meteoritics & Planetary Science, Vol. 40, p.87 (2005)


Diagram courtesy of J. N. Grossman & A. J. Brearley
Meteoritics & Planetary Science, Vol. 40, p.87 (2005)

In a manner similar to that employed for the chondrite groups, the eucrites have been petrologically divided into a metamorphic sequence comprising seven types (after Takeda and Graham, 1991; Yamaguchi et al., 1996):
  1. Type 1—most rapidly cooled within the sequence; mesostasis-rich with a glass phase and original chemistry preserved; exhibits pronounced Mg–Fe zoning in pyroxenes; represents the least altered basalt studied; e.g., clasts in Y-75011, Y-75015, and Y-74450

  2. Type 2—metastable Fe-rich pyroxenes are absent; mesostasis glass is no longer clear; e.g., Pasamonte

  3. Type 3—zoning from core to rim is less defined with an increase in Ca towards the rim; pyroxenes becoming cloudy; coarsening of pyroxenes resulting from augite exsolution lamellae; e.g., clast in Y-790266

  4. Type 4—only remnants of zoning still visible; cloudy pyroxenes present; mesostasis glass is recrystallized or absent; augite exsolution lamellae becoming resolvable in microprobe; e.g., Stannern, Nuevo Laredo

  5. Type 5—homogenous host composition with readily resolvable exsolved pigeonite lamellae; pigeonites extensively clouded by reheating; mesostasis glass recrystallized or absent; e.g., Juvinas, Sioux Co., Lakangaon

  6. Type 6—most slowly cooled eucrites in the sequence; the clinopyroxene pigeonite is partly inverted to orthopyroxene through slow cooling processes; pyroxenes contain Mg-rich cores and coarse augite exsolution lamellae; original mesostasis is absent; Ca is enriched in the rims; often have a brecciated texture; e.g., Millbillillie, Y-791186

  7. Type 7—recognized as the most metamorphosed in the sequence (Yamaguchi et al., 1996); e.g., Palo Blanco Creek, Jonzac, Haraiya, A-87272, NWA 3152

Weathering Grade (Cassidy, 1980; Otto, 1992)
(based on surficial rust and evaporites, used for Antarctic meteorites)

  • A–Minor rustiness; rust haloes on metal particles and rust stains along fractures are minor.
  • B–Moderate rustiness; large rust haloes occur on metal particles and rust stains on internal fractures are extensive.
  • C–Severe rustiness; metal particles have been mostly stained by rust throughout.
  • e–Evaporite minerals visible to the naked eye.

Weathering Grade (Wlotzka, 1993)
(based on oxidation of FeNi-metal and FeS, primarily used for ordinary chondrites)

  • W0–no visible oxidation of metal or sulfide but a limonitic staining may be noticeable in transmitted light. Fresh falls are usually of this grade, although some are already W1.
  • W1–minor oxide rims around metal and troilite, with minor oxide veins.
  • W2–moderate oxidation of metal, about 20–60% being affected.
  • W3–heavy oxidation of metal and troilite, 60–95% being replaced.
  • W4–complete (>95%) oxidation of metal and troilite, but no alteration of silicates.
  • W5–beginning alteration of mafic silicates, mainly along cracks.
  • W6–massive replacement of silicates by clay minerals and oxides.

Weathering Index (Rubin and Huber, 2005)
(based on the amount of staining in silicates, used for oxidized CK and R chondrites)

  • wi-0–unweathered; <5 vol% of silicates stained brown.
  • wi-1–slightly weathered; 5–25 vol% of silicates stained brown.
  • wi-2–moderately weathered; 25–50 vol% of silicates stained brown.
  • wi-3–significantly weathered; 50–75 vol% of silicates stained brown.
  • wi-4–highly weathered; 75–95 vol% of silicates stained brown.
  • wi-5–severely weathered; >95 vol% of silicates stained brown.
  • wi-6–extremely weathered; nearly complete staining of silicates, and significant replacement of mafic silicates by phyllosilicates.

Fracturing Scale

  • A–Minor cracks; few or no cracks are conspicuous to the naked eye and no cracks penetrate the entire specimen.
  • B–Moderate cracks; several cracks extend across exterior surfaces and the specimen can be readily broken along the cracks.
  • C–Severe cracks; specimen readily crumbles along cracks that are both extensive and abundant.

Age-Dependent Fragmentation and Dispersion in Hot Deserts (A. Al-Kathiri et al., 2005)

Fragmentation is considered to result from daily thermal fluctuations, volume increase, and penetration of sand and water into cracks. Dispersal occurs through natural means, i.e., wind and water, as well as by animals.

Fragmentation Index (FI):
the mass of the largest fragment ÷ total mass of all fragments
Fragment Dispersion (FD):
the maximum distance between different fragments of a single fall

Shock Stage* (olivine-bearing meteorites) (Stöffler et al., 1991; revised by Schmitt et al., 1994, Schmitt and Stöffler, 1995, and Rubin, 2004)

  • S1–S2: unshocked (sharp extinction of olivine grains), peak shock pressure <4–5 GPa, where 1 GPa = 10kb or 10,000 bars; min. temp. increase 10°C.
  • S2–S3: very weakly shocked (weak undulose extinction of olivine grains), peak shock pressure 5–10 GPa; min. temp. increase 20°C.
  • S3–S4: weakly shocked (strong undulose extinction in olivine grains with planar fractures and melt pockets; silicate darkening; irregular FeS in FeNi-metal; chromite veinlets and chromite–plagioclase assemblages; metallic Cu grains), peak shock pressure 10–15 GPa; min. temp. increase 100°C.
  • S4–S5: moderately shocked (mosaicism in olivine grains; some maskelynitization of feldspar; mobilization of metal and FeS in shock veins; narrow silicate melt veins; metal and sulfide nodules; polycrystalline troilite; melt pockets; mechanical twinning in Ca-rich clinopyroxene; martensite/plessite; high-pressure minerals), peak shock pressure 25–30 GPa; min. temp. increase 300°C.
  • S5–S6: strongly shocked (large impact-melt clasts present; high-pressure minerals), peak shock pressure 45–60 GPa; min. temp. increase 600°C.
  • S6: very strongly shocked (localized melt veins and maskelynite present; high-pressure minerals), peak shock pressure 60–75 GPa; min. temp. increase 1500°C (whole rock impact melting occurs at 75–90 GPa; temp. increase >1500°C).
*Shock stage is determined by the highest indicated stage by at least 25% of the indicator grains. In actuality, shock stage is determined by factors in addition to equilibrium shock pressure, including shock duration, pre-shock porosity, and stress-strain history (Xie et al., 2006).

Shock Stage (orthopyroxene-bearing meteorites) (Rubin et al., 1997), in conjunction with olivine and plagioclase data characterized by Stöffler et al., 1991; Schmitt et al., 1994; Schmitt and Stöffler, 1995; and Izawa et al., 2011)

  • S1: sharp optical extinction of orthopyroxene grains, peak shock pressure <5 GPa.
  • S2: undulose extinction of orthopyroxene grains, irregular fractures, peak shock pressure 5–10 GPa.
  • S3: clinoenstatite twinning parallel to (100), planar fractures, peak shock pressure 10–15 GPa.
  • S4: weak mosaicism in orthopyroxene grains, peak shock pressure 15–30 GPa.
  • S5: strong mosaicism, peak shock pressure 30–60 GPa.
  • S6 (only localized regions identified in enstatite chondrites): melting or transformation to majorite, peak shock pressure 75–90 GPa; (whole rock impact melting occurs at >90 GPa).

Shock Pressure Calibration (Schmitt, 2000)

A. SILICATES
  • <15 GPa: undulatory extinction of olivine.
  • 10–15 GPa to 20–25 GPa: weak mosaicism of olivine.
  • 20–25 GPa: onset of strong mosaicism of olivine.
  • 20–25 GPa (high-temperature conditions); 25–30 GPa (low-temperature conditions): transformation of oligoclase to diaplectic glass is complete.
  • 25–30 GPa (high-temperature conditions); 30–35 GPa (low-temperature conditions): onset of weak mosaicism in orthopyroxene.
  • 35–45 GPa (high-temperature conditions); 45–60 GPa (low-temperature conditions): start of recrystallization or melting of olivine.
  • >45–60 GPa (high-temperature conditions): recrystallization of olivine complete.
B. TROILITE
  • <25 GPa: undulatory extinction.
  • 25–45 GPa: twinning.
  • 30–60 GPa: partial recrystallization.
  • 10–45 GPa (high-temperature conditions); >35 GPa (low-temperature conditions): complete recrystallization.
  • >45 GPa (high-temperature conditions): melting and crystallization.
C. LOCALIZED SHOCK-INDUCED MELTING
  • >15 GPa (high-temperature conditions) or >30 GPa (low-temperature conditions): FeNi–FeS melt veins with pockets and veins of whole-rock melt.
When utilizing shock-melt veins, pressure calibrations for stage S6 of Stöffler et al. (1991) may be too high by a factor of at least two (Xie et al., 2006).

Chromite as a Shock Indicator (Rubin, 2003)

  • Shock Stage 1: Unmelted, unfractured chromite grains
  • Shock Stage 2: Unmelted, fractured chromite grains
  • Shock Stage 3: Chromite grains transected by opaque veins
  • Shock Stage 4: Chromite–plagioclase assemblages
  • Shock Stage 5: Veinlets containing chromite needles and blebs
  • Shock Stage 6: Chromite-rich chondrules
Rubin (2004) proposed that all equilibrated (type 4–6) ordinary chondrites were impact shocked to stage S3–S6, with subsequent annealing to an apparent shock stage of S1; some OCs experienced further shock events to acquire their present shock stage of S2–S6.

Shock Indicators in IVA Irons (Yang et al., 2011)

  • Shock Stage 1: M-shaped Ni profiles in taenite, Neumann twins in kamacite, cloudy taenite, monocrystalline troilite (e.g., Gibeon)
  • Shock Stage 2: M-shaped Ni profiles in taenite, shock-hatched kamacite, shock-melted troilite, cloudy taenite mostly lacking (e.g., Muonionalusta)
  • Shock Stage 3: Recrystallized lamellae, taenite microprecipitates on grain boundaries, completely shock-melted troilite (e.g., Maria Elena)
  • Shock Stage 4: Complete recrystallization of kamacite and taenite lamellae, lack of Thomson (Widmanstätten) structure, cloudy taenite completely absent (e.g., Fuzzy Creek)
Yang et al. (2011) proposed that IVA irons experienced three impacts: 1) a glancing impact 4.5 b.y. ago that ejected the silicate mantle and produced a 300 km-diameter molten metallic body; 2) a head-on collision occurred upon cooling to 200°C, likely producing a rubble-pile >30 km in diameter which resulted in shock reheating; 3) a final severe impact 400 m.y. ago producing a swarm of m-sized fragments and their delivery to Earth.

Meteorite Pairing (P. Benoit et al., 2000)

PAIRING CRITERIA:
Parent body history
Bulk elemental and isotopic concentrations
Mineral abundance and compositions
Petrography (shock, metamorphic, and igneous textures)
Stable isotope abundance and formation ages
Meteoroid space history
Cosmogenic noble gas ratios (cosmic-ray exposure age, shielding, solar gases, thermal history)
Natural TL (reheating)
Meteorite terrestrial history
Geographic proximity
Shape and size
Number of specimens
Terrestrial age
Weathering grade
Natural TL levels
Applying data from these criteria to the formula below, a pairing score and its associated pairing likelihood is obtained.

Prel = Prel* × Pss × Pbrec × Pcre × Psolar × P3He × Ptage × Pweath × PNatTL

where...
Prel* = relative abundance by classification
Pss = relative abundance by shock stage
Pbrec = relative abundance by brecciation
Pcre = relative abundance by cosmic-ray exposure age
Psolar = relative abundance by solar-gas-bearing meteorites
P3He = relative abundance by light noble gas depleted meteorites
Ptage = relative abundance by terrestrial age
Pweath = relative abundance by weathering factor
PNatTL = relative abundance by natural TL levels

Pairing score (%) / Pairing likelihood

>90_______Likely
80–90_____Probable
70–80_____Possible
50–70_____Potential
<50_______Candidate or Unlikely

Compositional Relationships Among Bodies
(Lindstrom et al., 1994; Mayne et al., 2008)

MINERAL COMPOSITIONS
  *Fe/Mn (pyx) plag. Fe-metal sulfide secondary alter.
HED 20–40 An90 Y Troilite none
Angrites 60–90 An99 N Troilite none
Moon 70 An92 Y Troilite none
Earth 60 An50 N Pyrrh. hydrous phases
Mars 35 An50 N Pyrrh. hydrous phases
Venus 55 N Pyrrh. anhydrous phases

*Differences in Fe/Mn ratios are attributed to initial accretional abundances. The primordial value of the Fe/Mn ratio in pyroxenes remains constant regardless of differentiation processes, and is considered to be diagnostic for the origin of each planetary body.

BULK CHEMICAL COMPOSITIONS
  Fe/Mn K/U K/La (×CI) Rb/La (×CI)
HED 30 (±2) 2,000 0.03 0.002–0.02
Ibitira 34–36
Angrites 80–95 150 0.002–0.03 0.001
Moon 62 (±18) 1,700 0.03 0.016
Earth 40 (±11) 12,500 0.15 0.09
Mars 35–50 15,000 0.2 0.3
Venus 55 (±30) 12,500 0.1–0.2 0.1

*O-ISOTOPIC COMPOSITIONS
  Δ17O (‰)
CR chondrites –0.96 to –2.42
Lodranites –0.85 to –1.49
Acapulcoites –0.85 to –1.22
Winonaites ~ –0.4 to –0.80
HED –0.24
Brachinites –0.13 to –0.30
Angrites –0.125
Moon 0.00
Earth 0.00
Mars +0.3
Venus +0.0 to +0.3
H (4–6) +0.73
L (4–6) +1.07
LL (4–6) +1.26

*Δ17O is a convenient measure of the vertical displacement of a data point from the terrestrial fractionation line:
Δ17O = δ17O – (0.52 × δ18O)
where δ17O = 17O/16O, and δ18O = 18O/16O, which are expressed as parts per thousand (per mil or ‰), and measured in terms of deviations from a standard (Standard Mean Ocean Water or SMOW)

e.g., δ18O = [(18Osample ÷ 16Osample) ÷ (18OSMOW ÷ 16OSMOW)] – 1
See an
oxygen 3-isotope plot

A report by E. Young (2007) concludes that optically thin photoactive regions in the outer disk were the site of CO photochemical conversion to 16O-poor, high Δ17O water ice. This 16O-poor water was transferred to the inner Solar System during the infall phase, or within a wavefront, on a timescale of 100 t.y. to 1 m.y., exchanging with the silicates and other chondrite constituents which formed subsequently in the inner Solar System; the igeous, refractory-rich CAI material that condensed prior to this water transfer remains 16O-rich.

Formational Relationships Among Ureilites (Cohen et al., 2004)

TOPICAL, CHEMICAL, AND ISOTOPIC PARAMETERS
Surface Depth
low formation pressure (~10–25 bars) high formation pressure (> ~100–125 bars)
highly reduced (smelting) little reduced (smelting suppressed)
low δ18O & Δ17O high δ18O & Δ17O
low C content high C content
magnesian (high Mg#; ~75–95) ferroan (low Mg#; ~60–90)
albitic melt clasts (<An25) labradoritic melt clasts (An39–58)
ol–aug melt clasts (An39–54)
ol–pig ureilite residues ol–aug ureilite residues

Accretion Process

Accretion from dust to planet occurred within 100 m.y. (Nuth III and Hill, 2004):

beginning with a single 100 nm-sized dust particle, × 1012 = 1 mm-sized pebble, × 1018 = 1 km-sized asteroid, × 109 = 1,000 km-sized planet... therefore, 1040 (~1 duodecillion) dust particles = 1 planet)

Accretion ages after CAIs, in m.y. (Sugiura and Fijiya, 2011, 2012):

magmatic irons=0.0 (±0.9)
pallasites=0.0 (±0.9)
mesosiderites=0.0 (±0.9)
HED=0.8 (±0.3)
angrites=0.5 (±0.4)
aubrites=<1.5
NWA 011=<1.5
ureilites=~1.0
acapulcoites=~1.2
Tafassasset=~2.0
chondrites: E=1.8; O=2.1; R=2.4; CK=2.6; CO=2.8; CV=3.0; CH/CB=3.3; CR=3.5; CM=~3.5; CI=~3.5

Melting/Differentiation Process

According to Sanders and Scott (2007), any body that accreted to a diameter >60 km (i.e., large enough to minimize heat loss from the surface through conduction) within ~2 m.y. after CAI formation (the oldest known objects dating to 4.567 b.y. ago) as the angrites did, must contain enough 26Al to produce global melting and differentiation. In contrast, Senshu and Matsui (2007) determined that accretion to a diameter of only ~14 km occurring within 2 m.y. after CAI formation was all that was required for global differentiation to occur, while accretion to a diameter of 40–160 km within 1.5 m.y. after CAI formation was cited by Hevey and Sanders (2006) and Sanders and Taylor (2005) as the minimums for differentiation. Sanders and Scott (2011) later revised that to suggest radiogenic melting proceeded in bodies >20 km in diameter that accreted within 1.5 m.y. after CAI formation, while bodies accreting later than 1.5 m.y. after CAIs were heated but not melted. Furthermore, they found that bodies which accreted later than 2.2 m.y. would not have melted at all. In addition, at large heliocentric distances (>~2.8 AU) accretion would proceed too slowly for sufficient 26Al to accumulate and initiate global melting prior to a body growing too large (~200 km diameter) for melting to be possible (Nyquist and Bogard, 2003).

Radiometric Dating

Visit Jim Hurley's informative webpage on the subject of Radiometric Dating.

SOME SHORT- AND LONG-LIVED CHRONOMETERS
Hibiya et al., 2014
Parent – Daughter Half-life Minerals dated
26Al → 26Mg 717 t.y. Plag – Olv,Pyx
60Fe → 60Ni 2.6 m.y. Chr – metal
53Mn → 53Cr 3.74 m.y. Olv – Chr
182Hf → 182W 8.9 m.y. Pyx – metal
92Nb → 92Zr 36 m.y. Pyx – Chr
146Sm → 142Nd 68 m.y. Chr,Pyx – Plag
176Lu → 176Hf 3.54 b.y. Pyx – Chr
87Rb → 87Sr 4.88 b.y. metal – Plag
147Sm → 143Nd 106 b.y. Chr,Pyx – Plag


CONTINUE TO
[PART I] Chondrites
[PART II] Achondrites
[PART III] Irons
[PART IV] Stony-Irons
[PART V] Refractory Phases
[APPENDECTOMY]


© 1997–2014 by David Weir