Iron with silicate inclusions, ungrouped
(COCV clan related)
no coordinates recorded
A rare Saharan iron meteorite weighing 2 kg was found near the border of Morocco and Algeria. The mass was obtained by G. Cintron of Island Meteorites, and a portion was sent for study to several institutions, including the Hawaii Institute of Geophysics & Planetology, the Institute of Geophysics and Planetary Physics in Los Angeles, the Enrico Fermi Institute in Chicago, the Universitat Bern in Switzerland, and Washington University in St. Louis. This meteorite contains sub-mm- to cm-sized, rounded, greenish-yellow, silicate inclusions dispersed throughout the metal host constituting ~44 vol%. Some of the silicates are aligned along shear planes that were probably created during an impact event.
Northwest Africa 176 is nearly identical to the meteorite Bocaiuva in elemental abundances, oxygen isotope composition, and petrographic features, and both were likely derived from the same parent bodyan asteroid with a composition similar to the COCV clan. Although the O-isotopic composition for both NWA 176 (Δ17O = 5.2) and Bocaiuva is similar to that of the IAB iron complex, they are clearly resolved from that group both by their significantly lower Au and As values (Wasson, 2011) and Mo isotope systematics (Budde et al., 2016). This O-isotopic value is also similar to the pallasites of the Eagle Station grouplet (see top diagram below), but the Ge and Ga contents are higher in these silicated irons which suggests an origin from similar chondritic material in the same region of the protoplanetary disk. Notably, utilizing a coupled Δ17O vs. ε54Cr diagram (see bottom diagram below), Sanborn et al. (2018) have demonstrated that Eagle Station plots closer to the CK (or CO) chondrite group. It could be inferred that both the CV and CK planetesimals experienced a similar petrogenetic history in a similar isotopic reservoir of the nascent Solar System.
Diagram credit: Greenwood et al., Chemie der Erde, vol. 77, p. 21, (2017)
'Melting and differentiation of early-formed asteroids: The perspective from high precision oxygen isotope studies'
(open access: http://dx.doi.org/10.1016/j.chemer.2016.09.005)
Chromium vs. Oxygen Isotope Plot
click on diagram for a magnified view
Diagram credit: Sanborn et al., 49th LPSC, #1780 (2018)
Northwest Africa 176 and Bocaiuva, along with the Eagle Station group pallasites, are resolved from the main-group pallasites and the major iron groups by their higher Ge/Ga ratios, higher Cu and Ir contents, and lower Au, As, and Sb contents. For those few irons that do have Ge/Ga ratios similar to NWA 176, in particular, the irons of group IIF and certain ungrouped irons such as the silicated iron Mbosi, their elemental abundance ratios rule against a genetic relationship with NWA 176 and its relatives. Nevertheless, it is likely they all originated from similar chondritic precursor material in the carbonaceous reservoir beyond Jupiter.
A multi-stage formation history is proposed for NWA 176 in which an initial impact generated enough heat (~1100°C) to form a melt pool. This was followed by gravitational differentiation that was sustained above ~500°C for a significant time. Differentiation resulted in a lower metallic layer with a cumulate silicate layer above. A subsequent impact event shattered the silicate layer and mobilized metal forcing it into existing cracks in the silicate layer, while initiating a rapid cooling phase at a rate of 1000°C/m.y. This cooling data would be consistent with a small body of only a few km in radius, or possibly reflects the breakup phase of a much larger object. Extended annealing at depth led to the rounding of the corners on silicate grains, a thermodynamic process acting to minimize the surface energy.
Several factors support this origin rather than the coremantle interface origin commonly envisioned for the main-group pallasites. The nearly chondritic silicate composition with its relatively low proportion of olivine is more consistent with an impact-melt model than for a coremantle interface origin. Moreover, the heat-generating radiogenic isotopes present in the later-forming carbonaceous chondrite parent bodies would be insufficient to produce melts that could form pallasitic compositions. Furthermore, the shear forces that produced the deformation features, as well as the loss of alkali volatiles, can be reconciled through impact mixing processes. Finally, the low Ir content of NWA 176 and its relatives is not consistent with fractional crystallization processes necessary for a coremantle origin. One possible alternative origin proposed for this meteorite is that the precursor was a metal-rich, highly metamorphosed, chondritic asteroid. Further details about possible origins of NWA 176 can be found on the Allende page.
Northwest Africa 176 has an absolute IXe age, calculated relative to Shallowater (4.5623 [±0.0004] b.y.), of ~4.544 (±0.007) b.y., indicating a relatively late formation, probably through impact processes (Bogard and Garrison, 2009). The meteorite has a remarkably high ArAr age of 4.524 (±0.013) b.y. The CRE age of 41 (±12) m.y. calculated for NWA 176 is low compared to other iron meteorites.
A portion of the information above was gleaned from the paper "BocaiuvaA Silicate-Inclusion Bearing Iron Meteorite Related To The Eagle-Station Pallasites" (Malvin, Wasson, Clayton, Mayeda, & Curvello), Meteoritics, vol. 20, #2, Part 1 (1985). The specimen of NWA 176 pictured above is an 8.07 g partial slice displaying rounded silicate inclusions. It's fresh dark fusion crust attests to a recent arrival.